Thunder is caused directly by lightning! Lightning bolts super-heat the air around them to tens of thousands of degrees. Warm air has a lower pressure, which creates a big shockwave in the air. Sounds are just waves travelling through the air, and the waves lightning produces are so massive they produce a huge RUMBLE of thunder!
Lightning is caused by the big turbulent towers of vertical motion in thunderstorms. This causes electric charges to build up, and when the difference in charge gets big enough of a bolt of electricity sparks off!
It happens because there is a lot of electric charges generated during an eruption and lightning happens because the charges are being balanced. Much like Angus describes below. What scientist don’t fully understand is where in the eruption the charges come from, inside the rocks, or is it from little dropplets of water in the ash?
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